Amber and Glass Flow
May 27, 2013
The better science fiction stories start with a relatively believable premise based on some scientific fact. In the days of Mary Shelley's Frankenstein novel, continuing up to the time of the best known Frankenstein film (Frankenstein, 1931, James Whale, Director), there was the idea of electricity as a vital force. It was by electricity that Victor Frankenstein was able to bring his monster to life. This idea still lingers in occult circles.
At the time of its writing in 1990, Michael Crichton's novel, Jurassic Park, had the believable plot device that dinosaur DNA could be extracted from mosquitoes preserved in amber, and that dinosaurs could then be cloned. This plotline, mixed with today's emphasis on making money from scientific knowledge, made for a great movie.
Although I wrote about fossil evidence of giant fleas sucking dinosaur blood in a previous article (Dino Farts and Fleas, May 16, 2012), even if dinosaur blood-sucking mosquitoes were well preserved in amber, the possibility of extracting dinosaur DNA is now thought to be impossible. The "half-life" of DNA is now estimated to be only about 500 years, so 150 million year old dinosaur DNA is now lost forever.[2-3]
Amber is fossilized tree resin. The resin consists of terpenes and trienes, which crosslink over the years into a hard polymer mass. One type of amber, Dominican amber, dates from Oligocene to Miocene, so it's about 25 million years old.
Although some specimens of amber may be crystal clear, amber isn't crystalline, it's a glass. The distinguishing property of a glass is its glass transition. Above the glass transition temperature, glass becomes a viscous liquid, and it can be manipulated, as by a glass blower.
One persistent legend involving window glass is that it continues to flow after its initial solidification. The evidence being provided is that newer window glass is flat, but window glass from cathedrals and the American colonial period are thicker at the bottom than the top.
Modern glass is produced by the float glass process in which the molten glass is formed on the surface of a pool of molten tin, so it's uniform in cross-section throughout. Windows from centuries ago were made from cut sections of glass produced by a spinning process. Spinning caused a thicker cross-section at the edge of the spun circle. Tradesmen would naturally mount the window panes with the thicker part downwards, since the thick edge makes a better base.
|A specimen of Dominican amber.|
(Photograph courtesy of Gregory McKenna, Texas Tech University)
There's abundant anecdotal evidence that flow of glass at room temperature doesn't happen. Arrowheads made from obsidian (volcanic glass) still have an edge after thousands of years. Glass artifacts have been discovered in Egyptian tombs in a state that appears to be what the artist intended. Furthermore, antique telescopes have no apparent distortion introduced by flow of the glass of their lenses. Edgar D. Zanotto published a 1998 paper "Do cathedral glasses flow?" debunking the cathedral glass legend.
Gregory B. McKenna of Texas Tech University presented the following calculation relating to the time scale for glass flow at room temperature.
|14th century Gothic rose window.|
If window glass did flow at a rapid rate, the fine detail in this window would have dulled after six centuries.
(Via Wikimedia Commons.)
• Silica glass has a viscosity of 1015.82 Pa-s at 1,000°C.
McKenna, a professor of chemical engineering at Texas Tech University is coauthor of a paper that extends experimental evidence on glass flow to a 20 million year time scale using measurements on amber.[7-9] Although amber is a polymeric glass, not an inorganic glass as in windows, glass dynamics follow the same laws. Joining him as authors are Texas Tech graduate student, Jing Zhao, and Sindee L. Simon, who is chair of the department.
• Using the reported activation energy, we can calculate that the viscosity at room temperature would be much greater than 1030 Pa-s.
• The Maxwell model allows an estimate of the relaxation time, τ, of a material as τ ≈ η0/G, where η0 is the initial viscosity and G is the shear modulus.
• Since G ≈ 28 GPa for window glass, then t ≈ 1012 years.
The study was undertaken as a result of experiments that Zhao had done on polyvinyl acetate for her qualifying examination for admittance to the Ph.D. program. The polyvinyl acetate results were unexpected, since they didn't show a divergence in the relaxation time. At that point, they decided to look at an older glass to extend the time scale of the investigation.
The Texas Tech team did a series of calorimetric and stress relaxation experiments on Dominican amber. Their measurement at various temperatures of the amber's relaxation time, the time it takes for the molecules to rearrange themselves, showed no divergence. This means that it wasn't acting as a fluid.[7,9] Internal rearrangement of the atoms in the amber specimens was found to have resulted in an increased material density of just 2.1% in 20 million years.[7,8]
Going for another order of magnitude in time scale, McKenna has obtained a piece of Triassic amber that's 220 million years old. This was provided by Eugenio Ragazzi, a professor in the Department of Pharmacology, the University of Padua, Italy.[8,10] This research was funded by the National Science Foundation under a grant from the Division of Materials Research.
|Jing Zhao and Gregory McKenna of Texas Tech University, two authors of the amber flow study.|
(Photograph courtesy of Gregory McKenna.)
- Frankenstein, 1931, James Whale, Director, on the Internet Movie Database).
- Morten E. Allentoft, Matthew Collins, David Harker, James Haile, Charlotte L. Oskam, Marie L. Hale, Paula F. Campos, Jose A. Samaniego, M. Thomas P. Gilbert, Eske Willerslev, Guojie Zhang, R. Paul Scofield, Richard N. Holdaway and Michael Bunce, "The half-life of DNA in bone: measuring decay kinetics in 158 dated fossils," Proc. R. Soc. B, vol. 279 no. 1748 (December 7, 2012), pp. 4724-4733.
- Matt Kaplan, "DNA has a 521-year half-life," Nature News, October 10, 2012, doi:10.1038/nature.2012.11555.
- Henry Halem, "Does Glass Flow? - The "Glass Flows" Myth," Glass Notes 4.0 Web Site.
- Edgar Dutra Zanotto, "Do cathedral glasses flow?" American Journal of Physics, vol. 66, no. 5 (May, 1998), pp. 392-395.
- Gregory B. McKenna, "Physical Aging in Glasses and Composites," Chapter 7 from Kishore V. Pochiraju, Gyaneshwar P. Tandon and Gregory A. Schoeppner, Eds., "Long-Term Durability of Polymeric Matrix Composites," Springer Science+Business Media, LLC, 2012, DOI 10.1007/978-1-4419-9308-3_7, pp. 237-309.
- Jing Zhao, Sindee L. Simon and Gregory B. McKenna, "Using 20-million-year-old amber to test the super-Arrhenius behaviour of glass-forming systems," Nature Communications, vol. 4, article no. 1783, April 30, 2013.
- Karin Slyker, "Fossil Amber Shatters Theories of Glass as a Liquid," Texas Tech University Press Release, May 7, 2013.
- George Dvorsky, "The 'glass is a liquid' myth has finally been destroyed," io9.com, May 8, 2013.
- Guido Roghi, Eugenio Ragazzi and Piero Gianolla, "Triassic Amber of the Southern Alps (Italy)," PALAIOS, vol. 21, no. 2 (April, 2006), pp. 143-154
Permanent Link to this article
Linked Keywords: Science fiction; science; scientific; Mary Shelley; Frankenstein; Frankenstein film; electricity; vital force; Victor Frankenstein; Frankenstein monster; occult; Michael Crichton; novel; Jurassic Park; dinosaur; DNA; mosquito; amber; cloning; clone; capitalism; making money; Jurassic Park film; fossil; flea; blood; half-life; year; resin; terpene; polyene; triene; polymer; Dominican amber; Oligocene; Miocene; transparent; crystal; crystallinity; crystalline; glass; glass transition; temperature; viscous liquid; glassblowing; glass blower; legend; soda-lime glass; window glass; cathedral; American colonial period; float glass; tin; cross-section; circle; tradesman; Wikimedia Commons; anecdotal evidence; room temperature; arrowhead; obsidian; volcanic glass; artifact; Egypt; Egyptian; tomb; artist; antique; telescope; distortion; lens; Edgar D. Zanotto; Gregory B. McKenna; Texas Tech University; calculation; silica glass; viscosity; pascal; Pa; second; s; Celsius; C; activation energy; Maxwell material; Maxwell model; relaxation time; material; shear modulus; GPa; professor; chemical engineering at Texas Tech University; experiment; polymer; polymeric; inorganic compound; dynamics; graduate student; Sindee L. Simon; chair; polyvinyl acetate; divergence; calorimetry; calorimetric; stress relaxation; molecule; fluid; density; order of magnitude; Triassic; Department of Pharmacology; University of Padua; National Science Foundation; Division of Materials Research; Frankenstein, 1931, James Whale, Director.
for your holiday gifts
Latest Books by Dev Gualtieri
Thanks to Cory Doctorow of BoingBoing for his favorable review of Secret Codes!
Blog Article Directory on a Single Page
- Gallium Nitride Tribology - December 1, 2016
- Lunar Origin - November 27, 2016
- Pumpkin Propagation - November 24, 2016
- Math Anxiety - November 21, 2016
- Borophene - November 17, 2016
- Forced Innovation - November 14, 2016
- Combating Glare - November 10, 2016
- Solar Tilt and Planet Nine - November 7, 2016
- The Proton Size Problem - November 3, 2016
- Coffee Acoustics and Espresso Foam - October 31, 2016
- SnIP - An Inorganic Double Helix - October 27, 2016
- Seymour Papert (1928-2016) - October 24, 2016
- Mapping the Milky Way - October 20, 2016
- Electromagnetic Shielding - October 17, 2016
- The Lunacy of the Cows - October 13, 2016
- Random Coprimes and Pi - October 10, 2016
- James Cronin (1931-2016) - October 6, 2016
- The Ubiquitous Helix - October 3, 2016
- The Five-Second Rule - September 29, 2016
- Resistor Networks - September 26, 2016
- Brown Dwarfs - September 22, 2016
- Intrusion Rheology - September 19, 2016
- Falsifiability - September 15, 2016
- Fifth Force - September 12, 2016
- Renal Crystal Growth - September 8, 2016
- The Normality of Pi - September 5, 2016
- Metering Electrical Power - September 1, 2016
- Transitioning to Utopia - August 29, 2016
- The Cheerios effect - August 25, 2016
- It's the Humidity - August 22, 2016
- Clinging to Theory - August 18, 2016
- Circumscribing Semicircles with Triangles - August 15, 2016
- Insecticidal Sweeteners - August 11, 2016
- Coffee Break - August 8, 2016
- Darker Matter - August 4, 2016
- Ten Rules of Statistics - August 1, 2016
- Shampoo - July 28, 2016
- The Happiness Equation - July 25, 2016
- The Planck Constant and the Kilogram - July 21, 2016
- Mars Landing 1976 - July 18, 2016
- Cartograms - July 14, 2016
- Alvin Toffler - July 11, 2016
- Rare Earth Metals from Fly Ash - July 7, 2016
- Harvard Metamaterial Flat lens - July 4, 2016
- Visualization in Science and Math - June 30, 2016
- Planet Nine - June 27, 2016
- Casting Lots in the Digital Age - June 23, 2016
- High-Entropy Alloys - June 20, 2016
- George Westinghouse - June 16, 2016
- Humidity Sensing - June 13, 2016
- Stellar Classification - June 9, 2016
- The Square Root of Two - June 6, 2016
- Fluidized Beds - June 2, 2016
- Memorial Day, Solomon Golomb - May 30, 2016
- Christiaan Huygens' Coupled Pendulums - May 26, 2016
- Side-Channel Attacks - May 23, 2016
- Seven Important Chemical Separations - May 19, 2016
- Antennas - May 16, 2016
- Avoided Numbers - May 12, 2016
- Analogy and Scientific Thought - May 9, 2016
- Smectic Martensite - May 5, 2016
- The Nanoscale Shakes - May 2, 2016
Deep Archive 2006-2008